期刊論文

學年 95
學期 2
出版(發表)日期 2007-07-01
作品名稱 Electronic Structure of Cobalt Nanocrystals Suspended in Liquid
作品名稱(其他語言)
著者 張經霖; Chang, C. L.; Liu, Hongjian; Guo, Jinghua; Yin, Yadong; Augustsson, Andreas; Dong, Chungli; Nordgren, Joseph; Chang, Chinglin; Alivisatos, Paul; Thornton, Geoff; Ogletree, D. Frank; Requejo, Felix G.; Groot, O Frank; Salmeron, Miquel
單位 淡江大學物理學系
出版者 American Chemical Society (ACS)
著錄名稱、卷期、頁數 Nano Letters 7(7), pp.1919-1922
摘要 The electronic structure of cobalt nanocrystals suspended in liquid as a function of size has been investigated using in situ X-ray absorption and emission spectroscopy. A sharp absorption peak associated with the ligand molecules is found that increases in intensity upon reducing the nanocrystal size. X-ray Raman features due to d−d and to charge-transfer excitations of ligand molecules are identified. The study reveals the local symmetry of the surface of ε-Co phase nanocrystals, which originates from a dynamic interaction between Co nanocrystals and surfactant + solvent molecules.
關鍵字
語言 en
ISSN 1530-6984
期刊性質 國內
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國別 TWN
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出版型式 ,電子版
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