期刊論文
| 學年 | 76 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 1988-06-01 |
| 作品名稱 | Electronic Conductivity in a New Class of Polyiodide Complexes of 5-Dibenzosuberenone with Iodine and Alkali Iodide |
| 作品名稱（其他語言） | |
| 著者 | Yang, H. S.; Wang, Chi-ming |
| 單位 | 淡江大學化學學系 |
| 出版者 | Taylor & Francis |
| 著錄名稱、卷期、頁數 | Molecular crystals and liquid crystals 159, pp.315-322 |
| 摘要 | A new class of polyiodide complexes of 5-dibenzosuberenone with iodine and alkali iodide (DIMI complexes, M = Na, K, Rb or Cs) has been prepared for the first time. The single crystals of the DIMI complexes are needle shaped with a shiny metallic luster along the needle axis. Their longitudial dc conductivities are in the order of 10−4 Scm−1 at room temperature. They behave in a semiconductive manner from 250 to 300 K with activation energies of 0.6 to 0.9 eV. Resonance Raman spectroscopic studies show that the iodine species exist as symmetric I3 − units in one-dimensional polyiodide chains, which are probably the conducting strands in these complexes. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 1542-1406 1543-5318 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24960 ) |