期刊論文

學年 88
學期 1
出版(發表)日期 1999-11-01
作品名稱 Anomalous Pr ordering and structural analysis for oxygenated tetragonal 1212 compound Pr1.5Ba1.5Cu3O7.2
作品名稱(其他語言)
著者 Ku, H. C.; Luo, H. M.; Chi, Y. P.; Lin, B. N.; Hsu, Y. Y.; Lee, T. J.; Shi, J. B.; 高惠春; Kao, H. C. I.
單位 淡江大學化學學系
出版者 Springer
著錄名稱、卷期、頁數 Journal of low temperature physics 117(3-4), pp.885-890
摘要 Magnetic measurement and powder X-ray Rietveld analysis are performed on oxygenated Pr1.5Ba1.5Cu3O7.2cuprate. This tetragonal compound with lattice parameters a = 0.38916 nm and c = 1.16177 nm is found to form the TlBa2CaCu2O71212-type structure when written as Cu[Ba1.5Pr0.5]PrCu2O7.2. Low temperature magnetic data indicate that anomalous Pr order temperature TN(Pr) decreases from 18 K for orthorhombic PrBa2Cu3O6.9to 10.5 K for Pr1.5Ba1.5Cu3O7.2. The increasing Pr-O bond length with decreasing TNindicates that Pr ordering is closely correlated with the wave function overlap between Pr-4f orbital and O-2pπorbital in the CuO2bi-layers.
關鍵字
語言 en
ISSN 0022-2291
期刊性質 國內
收錄於
產學合作
通訊作者
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國別 TWN
公開徵稿
出版型式 ,電子版
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